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Chemical interesterification of soybean oil and fully hydrogenated soybean oil: Influence of the reaction time

机译:大豆油和全氢化大豆油的化学酯交换反应:对反应时间的影响

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摘要

Chemical interesterification is an important alternative to produce zero trans fats. In practice, however, excessive reaction times are used to ensure complete randomization. This work evaluated the influence of the reaction time on the interesterification of soybean oil/fully hydrogenated soybean oil blend, carried out in the following conditions: 100 ºC, 500 rpm stirring speed, 0.4% (w/w) sodium methoxide catalyst. The triacylglycerol composition, solid fat content and melting point analysis showed that the reaction was very fast, reaching the equilibrium within 5 min. This result suggests the interesterification can be performed in substantially lower times, with reduction in process costs.
机译:化学酯交换是生产零反式脂肪的重要替代方法。然而,实际上,使用过多的反应时间来确保完全随机化。这项工作评估了反应时间对大豆油/完全氢化大豆油混合物酯交换作用的影响,该反应在以下条件下进行:100℃,500 rpm的搅拌速度,0.4%(w / w)的甲醇钠催化剂。三酰基甘油的组成,固体脂肪含量和熔点分析表明,该反应非常快,在5分钟内达到平衡。该结果表明,可以在更少的时间内进行酯交换,同时降低了工艺成本。

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